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Saturday, November 28, 2020 | History

1 edition of The catalytic vapor phase oxidation of pinene to maleic anhydride found in the catalog.

The catalytic vapor phase oxidation of pinene to maleic anhydride

  • 381 Want to read
  • 34 Currently reading

Published .
Written in English

    Subjects:
  • Terpenes

  • The Physical Object
    Pagination95 leaves
    Number of Pages95
    ID Numbers
    Open LibraryOL25925642M
    OCLC/WorldCa13369345

    Phthalic anhydride is made in the coking industry by the catalytic vapor-phase oxidation of naphthalene. The product is difficult to isolate from the reaction mixture leaving the static-bed catalytic reactors, since the volume of gases and vapors to be cooled is very large and the phthalic anhydride concentration in the mixture is very low.


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The catalytic vapor phase oxidation of pinene to maleic anhydride by Charles Kittredge Clark Download PDF EPUB FB2

Abstract A study has been made of the production of maleic acid by oxidation of benzene using various catalyst combinations supported on different Catalytic vapor-phase oxidation of 2,2,2-trifluoroethanol, Journal of Fluorine Chemistry, /j B.

Culbertson, Production of Maleic Anhydride, Maleic Anhydride, / Cited by: Oxidation of butane to maleic anhydride using a vanadium-phosphorus oxide catalyst, in oxidized form, wherein the resulting reduced catalyst is separately regenerated.

A recirculating solids reactor can be employed. Less than the stoichiometric amount of oxygen, based on the total amount of butane converted, can be by: This article is cited by 3 publications. Trivedi, B. Culbertson. Production of Maleic by: 3. JOUBNAL OF CATALYSIS 4, () A Study of the Catalytic Oxidation of Benzene to Maleic Anhydride BASIL DMUCHOVSKY, MARSHALL C.

FREERKS, EMILE D. PIERRON, RALPH H. MUNCH, AND FERDINAND B. ZIENTY From the Advanced Organic Chemicals Research Laboratory, Organic Chemicals Division, Monsanto Company, St. Louis, Missouri Received J ; revised Cited by: The oxidation of butane to maleic anhydride in a recirculating solids reactor using a stoichiometric excess of oxygen, a vanadium-phosphorus oxide catalyst in oxidized form, and separate regeneration of the resultant reduced catalyst is by: Manganese catalysts were investigated for the liquid-phase aerobic oxidation of α‐pinene.

First, the influence of reaction parameters such as time, solvent, temperature, oxidant flow rate and catalyst concentration on conversion, yield and selectivity were evaluated. Bhattacharyya et al. (), studying the catalytic vapor-phase oxidation of p- xylene and other hydrocarbons, report p- tolualdehyde, p-toluic acid and maleic anhydride as main products and traces of terephthalic acid and p-benzoquinone m fixed bed operation, and two additional products, namely terephthaldehydic acid and terephthaldehyde, using.

In producing maleic anhydride by catalytic oxidation of butane in vapor phase, the reaction mixture consists of butane and a recycle gaseous current made of compressed air and exhaust gas recovered from the absorption stage by a solvent of the maleic anhydride produced; oxygen and total butane concentration in the recycle stream are controlled.

BUTANE OXIDATION TO MALEIC ANHYDRIDE IN A RECIRCULATING SOLIDS RISER REACTOR R. CONTRACTOR Central Research and Development Department E. du Pont de Nemours and Co., Inc. Experimental Station, Wilmington, DEUSA ABSTRACT A recirculating solids riser reactor offers several advantages over fixed bed and fluidized bed reactors for vapor phase.

In producing maleic anhydride by catalytic oxidation of n-butane in vapor phase using oxygen or enriched air as oxidation medium, the reaction mixture consists of butane, oxygen and a recycling exhaust gas recovered from the absorption stage by a solvent of the maleic anhydride produced in the reaction.

In the instant process the carbon monoxide and the carbon dioxide concentration in the. In this project, the selective oxidation of benzene to maleic anhydride (MAN) was studied. Gas phase catalytic oxidation of benzene was carried out in a laboratory scale fluidized bed reactor on.

thalene and the production of maleic anhydride from benzene. Other examples of the commercial application of the process include the pro duction of both benzaldehyde and benzoic acid from toluene, anthra quinone from anthracene, various aldehydes and acids from the xylenes, and so on.1 The vapor phase oxidation of organic compounds is carried.

In this context, we present a novel, catalytic The catalytic vapor phase oxidation of pinene to maleic anhydride book for the synthesis of maleic anhydride (MA) via oxidative cleavage of the methyl carbon in LA over supported vanadates.

The approach is demonstrated in a continuous flow, packed bed reactor, and we have observed that VO x supported on SiO 2 achieves single-pass MA yields as high as 71%.

the vapor-phase oxidation of toluene by air, complete combus- tion occurs with cobalt and cerium oxides, while manganese, copper, nickel, chrom'um, and uranium are less active. Vana- dium oxide occupies an intermediate position and produces 1 The first two papers in this series appeared in (16) and (14).

The oxidation of C4 hydrocarbons has been studied over the active phase for butane oxidation to maleic anhydride, (V0)2P2O7 The activation of oxygen. Catalytic Oxidation Maleic Anhydride Molybdenum Oxide Vanadium Oxide Terephthalic Acid These keywords were added by machine and not by the authors.

This process is experimental and the keywords may be updated as the learning algorithm improves. Abstract. The first commercial process for MA production was put into use by National Aniline and Chemical in * It used the Weiss and Downs process employing benzene as a raw material.(1) InMonsanto made available MA which was a by-product of their phthalic anhydride manufacture.

Petrotex also used their butene-based process in the early s, which was later abandoned in favor. Über die Oxidation von o-Xylol an V2O5-Trägerkatalysatoren. Berichte der Bunsengesellschaft für physikalische Chemie84 (9), DOI: /bbpc B.

Mathur, D. Viswanath. Vapor phase oxidation of p-xylene. For example, the catalytic properties of supported Ni/TiO 2 heterogeneous catalysts prepared by the incipient wetness impregnation method were evaluated for the vapor phase hydrogenation of maleic. Maleic Anhydride is produced through an oxidation in a catalytic vapor phase of various hydrocarbons, and Benzene and C4 Hydrocarbons are usually its feedstock in commercial production.

A process for preparing a catalyst by selecting an active catalyst and contacting the active catalyst with one or more fluids containing an organic solvent or mixture of organic solvents.

In one embodiment, each organic solvent has a dielectric constant within a range of about 5 to about 55 when measured at a temperature of 20 DEG C to 25 DEG C. The oxidation of n-butane to maleic anhydride also has been compared by using fixedbed and membrane reactors with the same VPO catalyst.

The effects of operating conditions on the conversion of n-butane, the selectivity to maleic anhydride, and the yield of maleic anhydride.

Vapor-Phase Oxidation (Thermal, Catalytic, and Ultra-Violet) Description. Oxidation equipment is used for destroying contaminants in the exhaust gas from air strippers and soil vapor extraction (SVE) systems. There are three primary types of oxidation technologies used: thermal oxidation, catalytic oxidation, and ultra-violet (UV) oxidation.

Literature References: May be prepd by sublimation of maleic acid and P 2 O 5 under reduced pressure: Kempf, J. Prakt. Chem. [2] 78, (). Commercial production by catalytic vapor-phase oxidation of benzene or other suitable hydrocarbons: Weiss, Downs, Ind.

Eng. Chem. 12, (); US ( to Barrett Co.). Many other syntheses. Maleic anhydride is a classic substrate for Diels-Alder reactions. It was used for work inon the reaction between maleic anhydride and 1,3-butadiene, for which Otto Paul Hermann Diels and Kurt Alder were awarded the Nobel Prize in It is through this reaction that maleic anhydride converted to many pesticides and pharmaceuticals.

F Cavani, F Trifirò, Selective oxidation of light alkanes: interaction between the catalyst and the gas phase on different classes of catalytic materials, Catalysis Today, /S(99), 51,(), ().

Improved vapor phase catalytic oxidation of butane to maleic anhydride Oxidation of butane to maleic anhydride using a vanadium-phosphorus oxide catalyst, in oxidized form, wherein the resulting reduced catalyst is separately regenerated.

A recirculating solids reactor can be employed. Less than the stoichiometric amount of oxygen, based on. R.,A revision of the mechanism of o-xylene oxidation to phthalic anhydride with V/Ti/O catalysts, and the role of the promoter Cs, Catalysis oday,T – Chandrasekharan K. and Calderbank P.

H.,Kinetics of the catalytic air-oxidation of oxylene measured in a tube- -wall-catalytic. While its precursor maleic anhydride is typically synthesized by e.g.

vapor-phase oxidation of n-butane, recent reports show approaches for its naturally derived production [32, 33]. Maleic anhydride is used in the formulation of resins.

Exposure to maleic anhydride may occur from accidental releases to the environment or in workplaces where it is produced or used. Acute (short-term) inhalation exposure of humans to maleic anhydride has been observed to cause irritation of the respiratory tract and eye irritation.

The catalytic role of VO(H{sub 2}PO{sub 4}){sub 2}, the precursor of the VO(PO{sub 3}){sub 2} phase, has been studied for N-butane oxidation to maleic anhydride. By comparison with the activated VPO catalyst, derived from the VOHPO{sub 4} {center_dot} H{sub 2}O precursor phase, VO(H{sub 2}PO{sub 4}){sub 2} gives a highly selective final.

Originally, maleic anhydride was produced via air oxidation of benzene. With the increase in benzene costs, many new maleic anhydride plants have n-butane feeds Another reason for the switch from benzene to n-butane feed for maleic anhydride would be the additional cost to meet the proposed NESHAP regulation on benzene.

A process for recovering phthalic anhydride as a liquid from a vapor phase oxidation product which comprises mixing the vapor phase oxidation product having a temperature in the range of about ° C.

or greater with a first stream comprising maleic anhydride and/or at least one compound selected from the group consisting of: citraconic anhydride, benzoic acid and phthalic anhydride in a. Fumaric acid is a symmetrical molecule having no isomers and, therefore, the biological process offers no specific advantage over the chemical process.

Fumaric acid is presently produced by a chemical process through the isomerization of maleic acid (or maleic anhydride), obtained from a catalytic vapor-phase oxidation of benzene or C4.

For example, the catalytic properties of supported Ni/TiO 2 heterogeneous catalysts prepared by the incipient wetness impregnation method were evaluated for the vapor phase hydrogenation of maleic anhydride. It was discovered that the hydrogenation process of maleic anhydride is strongly affected by the calcination temperature of Ni/TiO 2.

“Vapor-Phase Catalytic Oxidation of Butane to Maleic Anhydride Using Oxygen Containing Gas in Stoichiometric Excess in Recirculating Solids Reactor with Vanadium-Phosphorus Oxide Catalyst, Removing Effluent, Separating Reduced Catalyst for Regeneration and Recycling,” U.S.

Patent 5, assigned to Du Pont, June 4, The vapor-phase oxidation of naphthalene to phthalic anhydride on a vanadium oxide catalyst can be represented by the following equation: catalyst.

rpV1 \Q + 2COz + 2H2O 4 1/2 02 naphthalene oxygen phthalic carbon water anhydride dioxide Theoretical yield is kg PAN/ kg naphthalene. It is important to recognize that there are no benzene emissions from any of the processes using n-butane or butenes, or from the recovery process from phthalic anhydride production, Benzene Oxidation Process Maleic anhydride is produced by the following vapor-phase chemical reaction: H-C - C" _^ II ^ + 2H2 + 2C02 2 H-C - C^Q BENZENE.

This chapter reviews the state-of-the-art about vanadium–phosphorus oxide (VPO) system employed as a heterogeneous catalyst in the selective oxidation of n-butane to maleic anhydride, which is the only industrial process of a selective vapor-phase oxidation of a light VPO system has been intensively studied over the last two decades and significant fundamental insights into the.

Mechanistic aspects of the gas-phase oxidation of n-pentane to maleic anhydride and phthalic anhydride, in: 1st European Chemistry Congress - Abstract Book, s.l, s.n,pp. 35 - 35 (atti di: 1st European Chemistry Congress, Budapest, agosto ) [atti di convegno-abstract].

One example mentioned in Chapter 9 is the production of maleic anhydride by selective oxidation of butane (Equation ). The commercial yield is only about 50%.

That is, about 4 moles of CO x are formed as reaction by-products for every mole of maleic anhydride produced. There is substantial room for improvement.anticipated from any process using n-butane or butenes, and none has been 9 found at lower detection limits of 1 ppmv. Benzene Oxidation Process Maleic anhydride is produced by the following vapor phase chemical reaction: 0 9/2 09 ^ II 0 + 2H0 + 2C0 L.

BENZENE OXYGEN MALEIC WATER CARBON ANHYDRIDE DIOXIDE The process flow diagram.Catalytic oxidation are processes that oxidize compounds using applications involve oxidation of organic compounds by the oxygen in air.

Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy. In petrochemistry, high-value intermediates such as carboxylic acids, aldehydes, ketones.